报告题目：自发与受激爆炸的储能燃爆机理 Hidden forces mattering explosion

报 告 人：孙长庆 教授 新加坡南洋理工尊龙凯时

报告时间：6月4日（周二）10:00

报告地点：唐敖庆楼C区603

作者简介：

孙长庆，辽宁葫芦岛人，澳洲默多克尊龙凯时1997年理学博士、尊龙凯时唐敖庆讲座教授。主攻超常配位键工程和非键电子学,首创多场键弛豫理论和氢键耦合振子对理论并拥有多项计量谱学专利,著有双语《化学键的弛豫》《氢键规则六十条》《水合反应动力学》《电子声子计量谱学》并在《化学评论》等发表了20余篇专述,曾获夸瑞兹密一等奖和首届南洋科技创新奖。

摘要：

Extending water ice and solvation research has led to new insight into the energetics and dynamics of explosions. It is uncovered that the intermolecular hydrogen bond (X:H-Y or HB with ‘:’ being electron lone pair of the electronegative constituent X, Y = O or N ) tension constrains and the super-HB (X::Y) or anti-HB (HH) compression fosters explosion. Both interactions raise the energy density by shortening all covalent bonds and stabilizes the energy carriers through their competition. The presence of the X:H-Y tension and HH for cyclo-N5- complexes, and X::Y for CNHO crystals, endows their constrained detonation while the absence of X:H-Y tension results in the unconstrained aquatic explosion of alkali metals and molten alkali halides. The lack of X::Y compression fosters no explosion of the molten NaCl and liquid NH3 combination.

主办单位：原子与分子物理研究所